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binol
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对于挥发性成分,毕澄茄中含有a-和β-型的O-乙基荜澄茄脂素(O-ethylcubebin)和5”-甲氧基扁柏内酯(5”-methoxyhinokinin),这些都是在特定环境下可能具有重要作用的成分。最后,还包含二氢荜澄茄脂素-4-乙酸酯(hemiariensin),胡椒环己烯酸(piperenol)A及B,以及长穗巴豆环氧
(66). Chen, X., Chen, W., Wang, L., Yu, X.-Q.*, Huang, D.-S., Pu, L.*, Synthesis of a C1 symmetric BINOL–terpyridine ligand and highly enantioselective methyl propiolate addition to aromatic aldehydes, Tetrahedron, 2010, 66, 1990–1993.(67). Chen, X., Liu, Q., Sun, H....
1. Guo-Hua Liu, Han Yu, Yun-Ning Xue, Mei Yao and Haibing Fang Synthesis, Crystal Structure of Chiral BINOL Derivatives and Its Application in the Enantioselective Lewis Acid Catalyzed Addition of Diethylzinc to Aldehydes. Chin. J. Struct. Chem. 2007, 26, 133-138.2. Guo-Hua...